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Mollie Elizabeth King was born in Wandsworth, Greater London, the youngest of three daughters born to Susan (née Wykes) and Stephen King, and attended Surbiton High School, in Kingston-upon-Thames, Greater London.
She has two sisters, Ellen and Laura. Mollie had a successful ski career and was on the Surbiton High Ski team with fellow pupil Chemmy Alcott. By age eleven, she was a member of the British Children’s Ski Team resulting in her receiving a scholarship to the British Ski Academy. King later raced for Great Britain as one of the youngest on the team and later went on to ski for the British Alpine squad although she turned down a ski career to pursue her dream of becoming a singer. Mollie achieved three As in her A levels, in Psychology, Business and Economics and Sport, despite suffering from dyslexia.